The amount of carbon dioxide in the earth's atmosphere grew at record rate in 2016 to a level not seen for millions of years, potentially fuelling a 20-metre rise in sea levels and adding 3degC to temperatures, the United Nations says.
Atmospheric concentrations of carbon dioxide (CO2), the main man-made greenhouse gas, hit 403.3 parts per million (ppm), up from 400.0 in 2015, the UN World Meteorological Organisation (WMO) said in its annual Greenhouse Gas Bulletin.
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That growth rate was 50 percent faster than the average over the past decade, driving CO2 levels 45 percent above pre-industrial levels and further outside the range of 180-280 ppm seen in recent cycles of ice ages and warmer periods.
"Today's CO2 concentration of 400 ppm exceeds the natural variability seen over hundreds of thousands of years," the WMO bulletin said.
The latest data adds to the urgency of a meeting in Bonn next month, when environment ministers from around the world will work on guidelines for the Paris climate accord backed by 195 countries in 2015.
The agreement is already under pressure because US President Donald Trump has said he plans to pull the United States out of the deal, which seeks to limit the rise in temperatures to "well below" 2degC above pre-industrial times.
Human CO2 emissions from sources such as coal, oil, cement and deforestation reached a record in 2016, and the El Nino weather pattern gave CO2 levels a further boost, the WMO said.
As far as scientists can tell, the world has never experienced a rise in carbon dioxide like that of recent decades, which has happened 100 times faster than when the world was emerging from the last ice age.
The last time carbon dioxide levels reached 400 ppm was 3-5 million years ago, in the mid-Pliocene era.